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Passive sampling - organic compounds

 
 
 

Passive sampling offers several advantages over conventional sampling. The sampler is in place for a longer period of time (often days or weeks), accumulating the analytes. The result is an average of the concentration during this time, which eliminates the risk of non-detection of, for example, occasional peaks in emitted pollutants.

PS Organic is our passive sampling method for non-polar organic compounds, such as PAH, PCB, and dioxins. The sampler consists of a stainless steel canister that holds from one to five membranes. These are mounted in so-called spider carriers. The canister and the spiders can be hired or purchased. Alternatively, a much smaller and simpler disposable canister, which holds one or two shorter membranes, can be used. There is also a well canister for use in groundwater sampling tubes. The membranes may also be mounted under a hood for air sampling. The hood can be placed directly on the ground or hanged e. g. in a tree.

The membrane contains a lipid which easily dissolves hydrophobic substances. The length of the sampling period is variable, but is often about one month. During this time organic pollutants in dissolved or gas phase diffuse through the membrane and accumulate in the lipid. This uptake mimics the accumulation of organic pollutants in, for example, fish. The organic compounds are then extracted from the membrane for subsequent chemical analysis by conventional methods. From the analytical result, concentrations in the sampled medium can be calculated.

PS Organic mounted on spider

 

Concentrations of lipid-soluble substances in water are often so low that direct chemical analysis is difficult, but the passive sampler provides substantial preconcentration and thus enables more reliable analyses. Due to the large capacity of the lipid, a relatively long time (often >1 month) will elapse before the sampler is saturated, i e before a state of equilibrium has been attained between sampler and water. This means that even polluted waters can be sampled with relative ease using PS Organic. Bioconcentration of lipid-soluble organic compounds may cause toxic concentrations of certain substances in aquatic organisms. Toxicity tests do not always take bioconcentration into account. In addition, several toxicity tests have low sensitivity for many common pollutants. This may result in false negative results in tests that are carried out directly on water. By combining toxicity tests with PS Organic, such problems can be avoided. Furthermore, it should be kept in mind that toxicity tests are sensitive even to substances that are not expected to occur in the sample.

Disposable deployment device

For more information on passive sampling, please contact Elsa Peinerud, phone +46 8 5277 5205 or Ingalill Rosén, +46 8 5277 5220.

 
 
Sampling equipment
 
PS Organic, standard size (91.4 cm)
PS Organic, 15.5 cm
Canister (for 2 spiders)
Spiders
Disposable deployment device
Canister for groundwater wells
Hood for air sampling
* In the event of loss, the price for purchase will be charged.
** This item is assembled and enclosed in a tin can when delivered.


 

 

 
 
PSO-1 Polycyclic aromatic hydrocarbons (PAH)
naphthalene benzo(a)anthracene
acenaphthylene chrysene
acenaphthene benzo(b)fluoranthene
fluorene benzo(k)fluoranthene
phenanthrene benzo(a)pyrene
anthracene dibenzo(ah)anthracene
fluoranthene benzo(ghi)perylene
pyrene indeno(123cd)pyrene
  The limits of quantification depend on the exposure time.
Method: HPLC-Fl/DAD, GC-MS. Uptake data available
.
 
 
PSO-2 Polychlorinated biphenyls (PCB)
PCB 28 PCB 138
PCB 52 PCB 153
PCB 101 PCB 180
PCB 118 Sum of 7 PCBs
  The limits of quantification depend on the exposure time.
Method: GC-ECD
. Uptake data available.
 
 
PSO-3 Organochlorinated pesticides (OCP)
alpha-HCH p,p'-DDT
beta-HCH o,p'-DDD
lindane (gamma-HCH) p,p'-DDD
delta-HCH o,p'-DDE
HCB p,p'-DDE
o,p'-DDT  
  The limits of quantification depend on the exposure time.
Method: GC-MS/MS. Uptake data available.
 
 
PSO-4 Dioxins and furans (PCDD/F)
2,3,7,8-tetraCDD 2,3,7,8-tetraCDF
1,2,3,7,8-pentaCDD 1,2,3,7,8-pentaCDF
1,2,3,4,7,8-hexaCDD 2,3,4,7,8-pentaCDF
1,2,3,6,7,8-hexaCDD 1,2,3,4,7,8-hexaCDF
1,2,3,7,8,9-hexaCDD 1,2,3,6,7,8-hexa-CDF
1,2,3,4,6,7,8-heptaCDD 1,2,3,7,8,9-hexaCDF
octachlorodibenzodioxin 2,3,4,6,7,8-hexaCDF
TCDD 1,2,3,4,6,7,8-heptaCDF
PeCDD 1,2,3,4,7,8,9-heptaCDF
HxCDD octachlorodibenzofuran
HpCDD TCDF
  PeCDF
  HxCDF
  HpCDF
  The limits of quantification depend on the exposure time. Uptake data available. Method: HRMS
 
 
PSO-5 Brominated flame retardants (PBDE)
BDE 28 BDE 153
BDE 47 BDE 154
BDE 99 BDE 183
  The limits of quantification depend on the exposure time.
Method: GC-MS/MS. Estimated uptake data available.
 
 
PSO-8 Aliphatics
Fraction C8-C10
Fraction C11-C16
Fraction C17-C24
Fraction C25-C36
  The limits of quantification depend on the exposure time.
Method: GC-FID
. Uptake data not available.
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